It's best to provide a plain white salt block (sodium chloride) without additional minerals, vitamins, or flavorings that the horse can access by choice 24/7. Horses need more sodium than any other mineral, and should be able to meet the need for it without having to ingest other minerals that are not needed. Palatability of water over winter is mostly about its temperature. I use heated water buckets which keep the water at drinking temperature and are very safe and easy to maintain. The heating unit is built into the walls of the bucket so it never needs cleaning, and the cord is housed in a flexible metal sheath. You can buy a 5 gallon flat back bucket for a stall or a 15 to 16 gallon bucket for more an area such as in a run in shelter. I actually use a 15 gallon heated bucket inside of my emptied water trough over winter since I tried trough heaters and they were a royal pain to maintain.
Anyway, I keep the salt block next to the trough so the horses are encouraged to use it and to drink more water, I also supply a trace mineral block to give them the choice, but horses only crave sodium chloride, so they use the mineral block much more rarely. My mineral block is not sweetened, which would encourage over-consumption.
Other than free choice access to a white salt block, electrolyte supplements should not be fed daily as a matter of routine. Feeding daily extra minerals such as calcium, for example, could limit his ability to mobilize calcium from his reserves when he needs it, and overfeeding of electrolytes has been linked to development of gastric ulcers. As a rule, you'd consider supplementing electrolytes a couple hours before stresses such as transporting and shows or heavier work than the horse is used to, or in hot weather and stressful conditions when horses sweat heavily and may dehydrate.
Most of what horses lose in sweat or use up during stress is sodium and potassium chloride. Unless your horse is involved in high stress activities or extreme sports, additional minerals in electrolyte supplements are seldom needed and can even be harmful.
Bicarbonates are added to some electrolyte supplements that are specially formulated for horses with diarrhea, but can be harmful for horses during periods of stress and exercise, so be sure you know what is in whatever products you use. if your horse is sweating profusely or working more than he's accustomed to, then electrolyte supplementation is warranted. Look for powders or pastes containing sodium chloride, potassium chloride, calcium chloride or calcium acetate, and magnesium. Sometimes I just mix regular table salt with lite salt which contains potassium chloride as well as sodium chloride which is sufficient to replace sodium and potassium chlorides lost through sweating or stresses.